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Effects of electrical discharges on the Mars´ atmosphere
Fojtíková, Nikola ; Horák, Jakub (referee) ; Kozáková, Zdenka (advisor)
The aim of this thesis was to study the effects of electric discharge on the atmosphere simu-lating conditions on Mars. This bachelor thesis is focused on simulation of Mars atmosphere at atmospheric pressure and normal laboratory temperature. Mars's atmosphere was more like Earth in the past. Mars is mostly composed of carbon dioxide, which accounts for more than 90% of Mars' atmosphere. To study the Mars atmosphere simulation, glow discharge generated in the reactor at atmospheric pressure was used at a CO2 flow (100 sccm) and dis-charge current of 20, 30 and 40 mA. A part of the measurements was focused on the influ-ence of hydrogen addition at different flow rates. The measurement time course with differ-ent measurement changes was also recorded. Reaction products were analysed using a pro-ton ion mass spectrometer and a flight time analyser. A high amount of aliphatic hydrocar-bons and their derivates, especially alcohols, was detected as well as several cyclic struc-tures. The main products identified in all experiments with a substantial concentration were molecules of ethen, ethane, ethanol, acetone, pentane, benzene and others.
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Diagnostics of plasma generated in the atmosphere simulating Mars
Fojtíková, Nikola ; RNDr. Martin Ferus, Ph.D., (referee) ; Kozáková, Zdenka (advisor)
The aim of the diploma thesis was the diagnostics of plasma generated in the atmosphere simulating conditions on Mars. This diploma thesis is focused on the simulation of Mars’ atmosphere at atmospheric pressure and normal laboratory temperature. Due to the similar conditions of Mars' atmosphere with Earth, this planet has been explored in the past as well as up to now. Mars' atmosphere is composed mostly of carbon dioxide, which makes up more than 90 % of Mars' atmosphere. A glow discharge generated in a special reactor at atmospheric pressure at a flow of pure CO2 was used to simulate the atmosphere of Mars. Part of the measurement was performed only in pure CO2 with changing current of 20, 25, 30, 35 and 40 mA. Part of the measurements was focused on the study of the effect of the addition of various gases, such as nitrogen, hydrogen and methane, at changes in their flow rates of 1, 2, 3, 4 and 5 sccm. The products formed in the special reactor were analysed using a mass spectrometer with proton ionization and with a flight time analyser. Optical emission spectrometry was used for plasma diagnostics and composition. Mainly simple aliphatic hydrocarbons, alcohols, aldehydes, and ketones were detected. With increasing flow rates of the individual gases, more complex aromatic compounds with higher molecular weights were formed. Corresponding mass and optical emission spectra were measured simultaneously.
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Influence of carbon monoxide on electrical discharge initiated processes in prebiotic atmospheres
Veselá, Jana ; Országh,, Juraj (referee) ; Krčma, František (advisor)
This work focuses on discharge-initiated processes in prebiotic atmospheres based on carbon monoxide. The aim of this work was to determine how the composition of different reaction mixtures consisting of carbon monoxide with gaseous additives influences type and amount of plasma-generated products. The compositions of gaseous products formed by a chemical reaction were investigated using mass spectrometry (proton transfer reaction ionisation with time-of-flight detector). The compositions of reactive particles presented in plasma were determined by using optical emission spectroscopy. The presence of many hydrocarbons, nitriles, amines, aldehydes and alcohols was confirmed by means of mass spectrometry in mixture containing 200 sccm carbon monoxide, 4 sccm hydrogen and 4 sccm nitrogen. Optical emission spectroscopy has shown that the main reactive particles in plasma were atomic hydrogen, carbon and oxygen, C2 molecule and CN radical. The presented properties can for example be used for enrichment of existing knowledge about prebiotic Earth atmosphere, chemical processes in interstellar mass and atmospheres of exoplanets. That´s because carbon monoxide is one of the most common molecules present in universe.
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Study of Positive Column in Glow Discharge under Medium Pressures Using Computational Experiment
Laca, Marek ; Hrachová, Věra (advisor) ; Novák, Stanislav (referee) ; Roučka, Štěpán (referee)
The positive column of the oxygen and argon-oxygen direct current glow discharge was investigated using a fluid plasma model at pressures around hundreds of pascals and discharge currents from ten to forty miliampers. The model describes the infinitely long positive column in cylindrical discharge tube. It is based on the continuity equation for particle concentration with the collisional right hand side. The model utilises the drift-diffusion approximation of particle flux and the mean-electron-energy approximation for the description of the electron interaction. The radial profile of particle concentration and interaction with the glass wall of the discharge tube is taken into account. The model predicts the electric field and the particle concentration in the positive column. The simulation results were compared with the measured intensity of electric field strength in the oxygen and argon-oxygen mixture. The impact of discharge conditions, like the pressure and gas composition, on the properties of the positive column was investigated. The model confirmed that the strength of longitudinal electric field at medium pressures is about 40 V/cm in oxygen, molecular gas, and it is about 3 V/cm in argon, noble gas.
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The Study of Transient Species and Precursors of Biomolecules using Spectroscopic Techniques
Ferus, Martin ; Civiš, Svatopluk (advisor) ; Šponerová, Judit E. (referee) ; Wild, Jan (referee)
The presented thesis is focused on a spectroscopic study of unstable radicals, ions and molecules in a positive column glow discharge and laser plasma. The research of these fragments is supplemented by a study of biomolecules formation from these species and influence of catalysts. Molecular dynamics of radicals, ions and unstable molecules has been studied using a time resolved Fourier transform infrared spectroscopy. Time resolved spectra of CH4, HCONH2, BrCN, CH3CN, CF3Br, (CF3)2CHBr positive column glow discharges have been measured and simulated using a kinetic model including molecular dynamics, collisions and chemical and radiation transfer processes. The model has been compared with our experimental results and time resolved spectra were described in details. Fit to a complex reaction mechanism has been used to estimate a rate constant of a HCN conversion to HNC by a collision with H radical. The study of precursors of biomolecules was focused on chemical consequences of a laser induced dielectric breakdown in formamide vapor and gaseous carbon monooxide with 18 O labeled water. Dissociation products have been detected using the Fourier transform absorption spectroscopy. The experimental results have been explained by a help of a chemical laser spark dynamics model. Additionally, our the...
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Diagnostics of plasma generated in the atmosphere simulating Mars
Fojtíková, Nikola ; RNDr. Martin Ferus, Ph.D., (referee) ; Kozáková, Zdenka (advisor)
The aim of the diploma thesis was the diagnostics of plasma generated in the atmosphere simulating conditions on Mars. This diploma thesis is focused on the simulation of Mars’ atmosphere at atmospheric pressure and normal laboratory temperature. Due to the similar conditions of Mars' atmosphere with Earth, this planet has been explored in the past as well as up to now. Mars' atmosphere is composed mostly of carbon dioxide, which makes up more than 90 % of Mars' atmosphere. A glow discharge generated in a special reactor at atmospheric pressure at a flow of pure CO2 was used to simulate the atmosphere of Mars. Part of the measurement was performed only in pure CO2 with changing current of 20, 25, 30, 35 and 40 mA. Part of the measurements was focused on the study of the effect of the addition of various gases, such as nitrogen, hydrogen and methane, at changes in their flow rates of 1, 2, 3, 4 and 5 sccm. The products formed in the special reactor were analysed using a mass spectrometer with proton ionization and with a flight time analyser. Optical emission spectrometry was used for plasma diagnostics and composition. Mainly simple aliphatic hydrocarbons, alcohols, aldehydes, and ketones were detected. With increasing flow rates of the individual gases, more complex aromatic compounds with higher molecular weights were formed. Corresponding mass and optical emission spectra were measured simultaneously.
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Study of Positive Column in Glow Discharge under Medium Pressures Using Computational Experiment
Laca, Marek ; Hrachová, Věra (advisor) ; Novák, Stanislav (referee) ; Roučka, Štěpán (referee)
The positive column of the oxygen and argon-oxygen direct current glow discharge was investigated using a fluid plasma model at pressures around hundreds of pascals and discharge currents from ten to forty miliampers. The model describes the infinitely long positive column in cylindrical discharge tube. It is based on the continuity equation for particle concentration with the collisional right hand side. The model utilises the drift-diffusion approximation of particle flux and the mean-electron-energy approximation for the description of the electron interaction. The radial profile of particle concentration and interaction with the glass wall of the discharge tube is taken into account. The model predicts the electric field and the particle concentration in the positive column. The simulation results were compared with the measured intensity of electric field strength in the oxygen and argon-oxygen mixture. The impact of discharge conditions, like the pressure and gas composition, on the properties of the positive column was investigated. The model confirmed that the strength of longitudinal electric field at medium pressures is about 40 V/cm in oxygen, molecular gas, and it is about 3 V/cm in argon, noble gas.
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Effects of electrical discharges on the Mars´ atmosphere
Fojtíková, Nikola ; Horák, Jakub (referee) ; Kozáková, Zdenka (advisor)
The aim of this thesis was to study the effects of electric discharge on the atmosphere simu-lating conditions on Mars. This bachelor thesis is focused on simulation of Mars atmosphere at atmospheric pressure and normal laboratory temperature. Mars's atmosphere was more like Earth in the past. Mars is mostly composed of carbon dioxide, which accounts for more than 90% of Mars' atmosphere. To study the Mars atmosphere simulation, glow discharge generated in the reactor at atmospheric pressure was used at a CO2 flow (100 sccm) and dis-charge current of 20, 30 and 40 mA. A part of the measurements was focused on the influ-ence of hydrogen addition at different flow rates. The measurement time course with differ-ent measurement changes was also recorded. Reaction products were analysed using a pro-ton ion mass spectrometer and a flight time analyser. A high amount of aliphatic hydrocar-bons and their derivates, especially alcohols, was detected as well as several cyclic struc-tures. The main products identified in all experiments with a substantial concentration were molecules of ethen, ethane, ethanol, acetone, pentane, benzene and others.
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Study of Glow Discharge in Oxygen and its Mixtures at Medium Pressures
Schmiedt, Lukáš ; Hrachová, Věra (advisor) ; Mazánková, Věra (referee) ; Novák, Stanislav (referee)
Title: Study of Glow Discharge in Oxygen and its Mixtures at Medium Pressures Author: Lukáš Schmiedt Department: Department of Surface and Plasma Science Supervisor: Doc. RNDr. Věra Hrachová, CSc. Department of Surface and Plasma Science Abstract: The positive column of DC glow discharge sustained in oxygen and oxygen-argon mixtures has been studied in two discharge tubes of the same shape made from different materials (Silica and Pyrex glass) for total pressures 200 - 1750 Pa and discharge currents up to 40 mA. Parameters of the discharge - electric field strength and emission spectra - were studied with respect to existence of the low- and high-gradient forms of the positive column of the discharge. We have focused on the qualitative analysis of the differences in emission spectra for both particular forms, as well as on possibility of determination of the rotational temperature of oxygen molecule under various discharge conditions, particularly with respect to the relative amount of the admixture. Keywords: glow discharge; oxygen; medium pressures; emission spectra
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The Study of Transient Species and Precursors of Biomolecules using Spectroscopic Techniques
Ferus, Martin ; Civiš, Svatopluk (advisor) ; Šponerová, Judit E. (referee) ; Wild, Jan (referee)
The presented thesis is focused on a spectroscopic study of unstable radicals, ions and molecules in a positive column glow discharge and laser plasma. The research of these fragments is supplemented by a study of biomolecules formation from these species and influence of catalysts. Molecular dynamics of radicals, ions and unstable molecules has been studied using a time resolved Fourier transform infrared spectroscopy. Time resolved spectra of CH4, HCONH2, BrCN, CH3CN, CF3Br, (CF3)2CHBr positive column glow discharges have been measured and simulated using a kinetic model including molecular dynamics, collisions and chemical and radiation transfer processes. The model has been compared with our experimental results and time resolved spectra were described in details. Fit to a complex reaction mechanism has been used to estimate a rate constant of a HCN conversion to HNC by a collision with H radical. The study of precursors of biomolecules was focused on chemical consequences of a laser induced dielectric breakdown in formamide vapor and gaseous carbon monooxide with 18 O labeled water. Dissociation products have been detected using the Fourier transform absorption spectroscopy. The experimental results have been explained by a help of a chemical laser spark dynamics model. Additionally, our the...
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